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碳基材料掺杂聚合物导电特性研究进展
引用本文:曹庆超,黄安平,张维,郑晓虎,肖志松,王小威,季君晖.碳基材料掺杂聚合物导电特性研究进展[J].高分子材料科学与工程,2012(4):177-181.
作者姓名:曹庆超  黄安平  张维  郑晓虎  肖志松  王小威  季君晖
作者单位:北京航空航天大学物理系;中国科学院理化技术研究所
基金项目:国家自然科学基金资助项目(50802005,51003114);教育部博士点基金(200800061055)
摘    要:导电聚合物可分为结构型导电聚合物和复合型导电聚合物,其中复合型导电聚合物主要是碳基材料或金属掺杂聚合物而得到。文中综述了碳基材料掺杂聚合物的导电机理和碳基材料掺杂聚合物导电特性的研究进展。导电机理主要有渗滤理论、隧道效应和场致发射理论等。目前应用于复合型导电聚合物的碳基材料主要为炭黑、碳纳米管和石墨烯等。文中还简要介绍了碳基材料掺杂聚合物的应用和发展趋势。

关 键 词:聚合物  掺杂  碳纳米管  石墨烯  导电机理

Progress in Conductive Properties of Carbon-Based Doped Polymer
Qingchao Cao,Anping Huang,Wei Zhang,Xiaohu Zheng,Zhisong Xiao,Xiaowei Wang,Junhui Ji.Progress in Conductive Properties of Carbon-Based Doped Polymer[J].Polymer Materials Science & Engineering,2012(4):177-181.
Authors:Qingchao Cao  Anping Huang  Wei Zhang  Xiaohu Zheng  Zhisong Xiao  Xiaowei Wang  Junhui Ji
Affiliation:1.Department of Physics,Beihang University,Beijing 100191,China;2.Technical Institute of Physics and Chemistry,Chinese Academy of Sciences,Beijing 100190,China)
Abstract:Conductive polymer has attracted widespread attention since its emergence.It can be classified by two categories which are structural conductive polymer and filling conductive polymer composite,respectively.Among them,the filling conductive polymer composite can be obtained by doping carbonaceous material or metal. In this article,the conductive mechanism of conductive polymer composite doped by carbon-based material and progress in its conductive properties has been reviewed.The conductive mechanism contains percolation theory,tunneling effect and field emission.Generally,carbon-based conductive fillers include carbon black,carbon nanotube and graphene.Besides,the application and future trend of carbon-based doped conductive polymer were also introduced briefly.
Keywords:polymer  doped  carbon nanotube  graphene  conductive mechanism
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