Kinetics of Solid-State Reactions in Heterogeneous Catalysis from Time-Resolved X-Ray Absorption Spectroscopy |
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Authors: | Ressler Thorsten Wienold Julia Jentoft Rolf E Neisius Thomas Günter Marco M |
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Affiliation: | (1) Department of Inorganic Chemistry, Fritz-Haber-Institut der Max-Planck-Gesellschaft, Faradayweg 4-6, D-14195 Berlin, Germany;(2) European Synchrotron Radiation Facility, BP 220, F-38043 Grenoble, France |
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Abstract: | The potentials of X-ray absorption spectroscopy (XAS) (quantitative phase composition and average valence together with a short-range order structure analysis) combined with a time-resolution in the second range make time-resolved (TR-) XAS a powerful tool for investigating the reactivity of solids in catalysis and solid-state chemistry. General aspects of TR-XAS investigations are discussed (i.e., instrumentation, data analysis). In addition, some experiments illustrate how the kinetics of solid-state reactions in heterogeneous catalysis can be elucidated from TR-XAS studies. |
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Keywords: | in situ time-resolved XAS solid state kinetics molybdenum copper |
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