Preparation and luminescence properties of europium complex with α-naphthylacetic acid incorporated in silica matrix by sol-gel method |
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作者姓名: | 陈野 蔡伟民 孙晓君 崔丹 于英宁 |
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作者单位: | [1]Dept.ofEnvironmentalScienceandEngineering,HarbinInstituteofTechnology,Harbin150001,China [2]Dept.ofChemistry,HeilongjiangUniversity,Harbin150080,China [3]KeyLaboratoryofRareEarthChemicalandPhysics,ChangchunInstituteofChemistry,Changchun130022,China |
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摘 要: | Europium ternary complex of Eu (NNA)3 (NNA =α-naphthylacetic acid) was embedded in silica matrix at different ratios by sol-gel method. The luminescence properties of silica composites were studied by comparing them with those of corresponding pure complex by means of excitation, emission spectra and lifetimes. The fluorescence lifetime was prolonged when the pure complex was incorporated in silica matrix. The relative fluorescence intensity and fluorescence lifetimes increased simultaneously with the increase of Eu(NNA)3.
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关 键 词: | 铒 发光性 溶胶凝胶法 发射谱 荧光光谱 |
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