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Preparation of alinite cement from municipal solid waste incineration fly ash
Authors:Kai Wu  Huisheng Shi  Geert De SchutterXiaolu Guo  Guang Ye
Affiliation:a Key Laboratory of Advanced Civil Engineering Materials (Tongji University), Ministry of Education, 4800 Caoan Road, Shanghai 201804, China
b Magnel Laboratory for Concrete Research, Department of Structural Engineering, Ghent University, Technologiepark-Zwijinaarde 904, Ghent 9052, Belgium
c Microlab, Faculty of Civil Engineering and Geosciences, Delft University of Technology, Stevinweg 1, 2628 CN Delft, The Netherlands
Abstract:
The feasibility of partially substituting ordinary raw materials with municipal solid waste incineration (MSWI) fly ash in alinite cement production was investigated by X-ray diffraction (XRD), X-ray fluorescence spectrometry (XRF) and scanning electron microscopy (SEM). The physical properties and leaching behavior of the produced cement were also evaluated. Experimental results show that good quality clinkers can be obtained by firing the raw mixes, in which the replacement of MSWI fly ash reaches to 30%, at 1200 °C for 2 h. Alinite cements have higher early strengths at all gypsum additions, while the best result having acceptable early and 28-day strengths is obtained at 5% of gypsum addition. Results also show that the leaching toxicity of heavy metals is far lower than that of the regulatory limit at all testing ages. Based on this study, MSWI fly ash is viable as an effective, alternative raw material in alinite cement production.
Keywords:MSWI, municipal solid waste incineration   XRD, X-ray diffraction   XRF, X-ray fluorescence spectrometry   SEM, scanning electron microscopy   EDS, energy disperse spectroscopy   ICP-AES, inductively coupled plasma atomic emission spectrophotometer   KH, lime saturation moduli   a, silica-alumina ratio   c, silica-chloride ratio
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