| 芳基重氮化合物与烯胺的合成反应研究 |
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| 引用本文： | 耿小兰,赵伟杰.芳基重氮化合物与烯胺的合成反应研究[J].云南化工,2006,33(3):11-13. |
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| 作者姓名： | 耿小兰 赵伟杰 |
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| 作者单位： | 1. 徐州医药高等职业学校,江苏,徐州,221116
2. 黄淮学院,化学化工系,河南,驻马店,463000 |
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| 摘 要： | α-重氮苯乙酸酯与N-(苯乙烯基)-吗啉在铜盐催化下的反应,能够以高的化学产率制备手性γ-酮酯。详细讨论了γ-酮酯的制备方法、烯胺的结构对反应的影响。
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| 关 键 词： | γ-酮酯 烯胺 芳基重氮化合物 过渡金属催化剂 |
| 文章编号： | 1004-275X（2006）03-0011-03 |
| 收稿时间： | 2006-02-27 |
| 修稿时间： | 2006-02-27 |
Study on Reaction of Methyl Phenyldiazoacetate with Enamines |
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| GENG Xiao-lan,ZHAO Wei-jie.Study on Reaction of Methyl Phenyldiazoacetate with Enamines[J].Yunnan Chemical Technology,2006,33(3):11-13. |
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| Authors: | GENG Xiao-lan ZHAO Wei-jie |
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| Affiliation: | 1. Xuzhou Medical Vocational School, Xuzhou 221116, China; 2. Department of Chemistry and Chemical Engineering, Huanghuai College, Zhumadian 463000, China |
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| Abstract: | Reaction of methyl phenyldiazoacetates with N-(1-styryl)morpholine catalyzed by copper salt was studied and the yield of chiralγ-keto ester was high.Preparation of γ-keto ester and effect of enamines on the reaction was also investigated. |
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| Keywords: | γ-ketoester enamine aryldiazoacetate catalyst of transition metal |
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