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四氯乙烷脱氯化氢制三氯乙烯所用催化剂的影响因素
引用本文:许志华,郭洪新,周本荣.四氯乙烷脱氯化氢制三氯乙烯所用催化剂的影响因素[J].氯碱工业,2008,44(1):31-35.
作者姓名:许志华  郭洪新  周本荣
作者单位:葫芦岛益鑫精细化工有限公司,辽宁,葫芦岛,125001
摘    要:探讨了四氯乙烷脱氯化氢制三氯乙烯所用催化剂的制备方法、反应器材质、氯化铁、原料四氯乙烷中的杂质1,1,2-三氯乙烷和高沸物及操作条件对催化剂的影响,从而指导四氯乙烷脱氯化氢制三氯乙烯的工业生产,提高催化剂的效率,延长催化剂的寿命,消除不利的影响因素,提高产品质量,降低生产成本,确保三氯乙烯生产的长期、稳定运行.

关 键 词:三氯乙烯  四氯乙烷  脱氯化氢  催化剂  氯化铁  1  1  2-三氯乙烷
文章编号:1008-133X(2008)01-0031-05
修稿时间:2007年8月30日

Influential factors of the catalysts in trichloroethylene preparation by dehydrochlorination from tetrachloroethane
XU Zhi-hua,GUO Hong-xin,ZHOU Ben-rong.Influential factors of the catalysts in trichloroethylene preparation by dehydrochlorination from tetrachloroethane[J].Chlor-Alkali Industry,2008,44(1):31-35.
Authors:XU Zhi-hua  GUO Hong-xin  ZHOU Ben-rong
Abstract:It is discussed that how the preparation methods of the catalyst for trichloroethylene by dehydrochlorination from tetrachloroethane,the reactor materials,ferric chloride,the impurity 1,1,2-trichloroethane and the high boilers contained in raw material tetrachloroethane and the operating conditions influence the catalyst.Therefore,the results can instruct the industrialization production of trichloroethy-lene by dehydrochlorination from tetrachloroethane,promote the catalyst efficiency,prolong the catalyst life,eliminate the adverse factors,reduce production cost and ensure the production of trichloroethylene with long-term and steady running.
Keywords:trichloroethylene  tetrachloroethane  dehydrochlorination  catalyst  ferric chloride  1  1  2-trichloroethane
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