| 二苯羟乙酸糖酯酶促合成研究 |
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| 引用本文： | 王宗君,胡文祥,张良军. 二苯羟乙酸糖酯酶促合成研究[J]. 当代化工, 2010, 39(1): 17-19 |
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| 作者姓名： | 王宗君 胡文祥 张良军 |
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| 作者单位： | 广西工业职业技术学院,广西,南宁530001;军事医学科学院,北京,100850 |
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| 摘 要： | 二苯羟乙酸衍生物及糖类化合物分别具有重要的生理功能，二苯羟乙酸糖酯有可能同样具有一定的生理价值。着重对这类化合物的酶促合成进行探讨，选择定位合成二苯羟乙酸糖酯，收率达26％。
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| 关 键 词： | 二苯羟乙酸糖酯 酶促合成 选择定位 |
Study on Enzymatic Synthesis of Sugar Esters of Benzilic Acid |
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| WANG Zong-jun,HU Wen-xiang,ZHANG Liang-jun. Study on Enzymatic Synthesis of Sugar Esters of Benzilic Acid[J]. Contemporary Chemical Industry, 2010, 39(1): 17-19 |
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| Authors: | WANG Zong-jun HU Wen-xiang ZHANG Liang-jun |
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| Affiliation: | 1. Guangxi Vocational ＆ Technical Institute of Industry, Guangxi Nanning 530001, China; 2.Academy of Military Medical Sciences, Beijing 100850, China) |
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| Abstract: | The derivatives of benzilic acid and fructose are significan in life sciences. Carbohdrate molecules represent a particularly challenging target for regioselective modifications due to their multitive hydroxyl groups. The 1-fructopyranosyl benzilate was synthesized by enzyme-catalyzed regioselective etherification of fi＇uctose and actived esters of diphenyl glycolic acid in anhydrous pyridine with porcine pancreatic lipase.The yield of the product was 26%. |
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| Keywords: | Sugar Esters of Benzilic Acid Enzymatic Synthesis Regioselective |
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