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Highly hydrogen-deficient hydrocarbon species for the CO2-reforming of CH4 on Co/Al2O3 catalyst
Authors:Toshihiko Osaki  Hiroyuki Masuda  Tatsuro Horiuchi  Toshiaki Mori
Affiliation:(1) National Industrial Research Institute of Nagoya, Hiratecho, Kitaku, 462 Nagoya, Japan
Abstract:The dynamics of produced CO and H2, measured by pulse surface reaction rate analysis (PSRA), revealed that the intermediate hydrocarbon species for the CO2-reforming of CH4 was highly hydrogen-deficient (CH0.75) on supported Co/Al2O3 catalyst. It was also found that the species was more reactive than the less hydrogen-deficient one (CH2.4) on Ni/Al2O3 catalyst.
Keywords:CO2-reforming  Co/Al2O3  pulse reaction  rate analysis  reaction intermediate
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