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Formation of Silicalite-1 in Channels of Novel SiO2–ZrO2 Porous Glass Tubes Used as Both a Silica Source and a Substrate
Authors:Tetsuro Jin  Koji Kuraoka  Yasuyuki Matsumura  Takaaki Onishi  Tetsuo Yazawa
Affiliation:National Institute of Advanced Industrial Science and Technology, AIST Kansai, 1-8-31 Midorigaoka, Ikeda, Osaka 563–8577, Japan;Kubota Corporation, Ryugasaki, Ibaraki 301-0852, Japan
Abstract:Silicalite-1 has been prepared using a novel SiO2–ZrO2 porous glass tube as both a silica source and a substrate. The SiO2–ZrO2 glass tube was found to possess sufficient physical strength to enable practical use as a separation and catalytic membrane after silicate-1 deposition within its channel. This is in contrast to porous SiO2 glass which cannot be used to synthesize a silicalite-1 deposited membrane with enough physical strength to perform gas permeance measurements.
Keywords:silica    pores/porosity    glass
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