| 还原条件对三元载体加氢催化剂加氢脱氮性能的影响 |
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| 引用本文： | 顾永和,吕罡,崔超,王其舟,鲁凤,王守伟.还原条件对三元载体加氢催化剂加氢脱氮性能的影响[J].当代化工,2012(11):1174-1176. |
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| 作者姓名： | 顾永和 吕罡 崔超 王其舟 鲁凤 王守伟 |
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| 作者单位： | 兰州石化职业技术学院;辽宁省抚顺市石油二厂;新疆独山子石化公司 |
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| 摘 要： | 用原位溶胶凝胶法制备了不同TiO：含量的MoP／TiO2-SiO2-Al2O3催化剂，对含喹啉的模型化合物，在连续同定床反应器上进行。THDN活性评价（反应温度为300～400℃，反应压力为3．0MPa）。在不同还原条件下，对催化剂进行加氢脱氮活性评价。结果表明：还原条件对MoP／TiO2-SiO2-Al2O3催化剂加氢活性有较大影响，评价确定的最佳还原条件为：还原气速60mL／min，还原温度为600℃。
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| 关 键 词： | MoP TiO2-SiO2-Al2O3 加氢脱氮 |
Effect of Reduction Conditions on Hydrodenitrogenation Activity of MoP/TiO2-SiO2-Al2O3 Catalysts |
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| GU Yong-he,LV Gang,CUI Cao,WANG Qi-zhou,LU Feng,WANG Shou-wei.Effect of Reduction Conditions on Hydrodenitrogenation Activity of MoP/TiO2-SiO2-Al2O3 Catalysts[J].Contemporary Chemical Industry,2012(11):1174-1176. |
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| Authors: | GU Yong-he LV Gang CUI Cao WANG Qi-zhou LU Feng WANG Shou-wei |
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| Affiliation: | 1(1.Lanzhou Petrochemical College of Vocational Technology,Gansu Lanzhou 730060,China;2.Fushun Petrochemical Company Refinery No.2 of CNPC,Liaoning Fushun 113004,China;3.PetroChina Dushanzi Petrochemical Company,Xinjiang Dushanzi 833600,China) |
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| Abstract: | MoP/TiO2-SiO2-Al2O3 catalysts with different TiO2 contents were prepared by insitu sol-gel method.On a model compound of quinoline, hydrodenitrogenation（ HDN）activity of the catalysts was tested in a fixed bed reactor. The results show that the optimum conditions of the in situ reduction are as follows：H2 flow rate is 60 ml/min and reduction temperature is 600℃. |
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| Keywords: | MoP TiO2-SiO2-Al2O3 HDN |
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