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Catalytic upgrading of woody biomass derived pyrolysis vapours over iron modified zeolites in a dual-fluidized bed reactor |
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| Authors: | A. Aho A.V. Lashkul M. Ziolek T. Salmi M. Hupa |
| Affiliation: | a Laboratory of Industrial Chemistry and Reaction Engineering, Åbo Akademi University, FI-20500 Åbo/Turku, Finland b Laboratory of Wood and Paper Chemistry, Åbo Akademi University, FI-20500 Åbo/Turku, Finland c Laboratory of Inorganic Chemistry, Åbo Akademi University, FI-20500 Åbo/Turku, Finland d A. Mickiewicz University, Faculty of Chemistry, 60-780 Poznan, Poland e Department of Mathematics and Physics, Lappeenranta University of Technology, P.O. Box 20, 53851 Lappeenranta, Finland |
| Abstract: | In this paper, the influence of the proton forms of beta, Y and ferrierite zeolites and their iron modified counterparts during upgrading of pine wood pyrolysis vapours under nitrogen atmosphere was investigated. A dual-fluidized bed reactor was used where in the first bed pyrolysis of pine wood occurred, and in the second upgrading of the pyrolysis vapours over zeolites was conducted. The temperature for pyrolysis and upgrading was 400 and 450 °C, respectively. De-oxygenation reactions over the proton form and iron modified zeolites increased compared to the non-catalytic pyrolysis. The increased selectivity towards organic compounds through de-oxygenation could be noticed as a higher water yield and CO formation. |
| Keywords: | pyrolysis biomass iron modification fluidized bed reactor |
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