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Na2S-SO2反应体系中H2S产生的过饱和态分析
引用本文:吴高明,沈士德,童仕唐.Na2S-SO2反应体系中H2S产生的过饱和态分析[J].化学工程师,2002(5):19-21.
作者姓名:吴高明  沈士德  童仕唐
作者单位:1. 武汉钢铁(集团)公司,湖北,430082
2. 武汉科技大学,湖北,430083
摘    要:向Na2S溶液中通入低浓度SO2气体以生成H2S,H2S从液相中逸出时,存在一突跃现象。本文根据这一现象,结合Y.T.Shah等提出的吸收-反应-解吸体系中过饱和态存在的条件,通过理论分析,得出在Na2S-SO2-H2S4反应体系中H2S解吸存在过饱和现象。

关 键 词:Na2S-SO2反应体系  硫化钠  硫化氢  解吸  过饱和现象
文章编号:1002-1124(2002)05-0019-03
修稿时间:2002年4月1日

Anolysis of Supersaturation of Hydrogen Sulfide Desorption in the Reaction System of Na2S- SO2
Wu Gaoming,Shen Shide,Tong Shitang.Anolysis of Supersaturation of Hydrogen Sulfide Desorption in the Reaction System of Na2S- SO2[J].Chemical Engineer,2002(5):19-21.
Authors:Wu Gaoming  Shen Shide  Tong Shitang
Affiliation:1 Wuhan Iron and Steel Co Hubie 430082;2 Wuhan University of Science and Technology Hubie 430083
Abstract:In the reaction system in which dilute sulfur dioxide is absorped into aqueous sodium sulfide solution and simultaneously hydrogen sulfide is desorped from the solution,the beginning gaseous concentration of hydrogen sulfide desorption from solution increased suddenly.In the light of this phenomenon and the supersaturation condition which is illustrated by Y.T.Shah's et al.for the system of absorption-reaction-desorption,based on the theoretic analysis,this paper came to the conclusion that in the course of hydrogen sulfide desorption there is a supersaturation phenomenon in the reaction system of Na 2S-SO 2 H 2S
Keywords:Sodium sulfide  Hydrogen sulfide  Desorption  Supersaturation phenomenon
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