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ZnO photoanodes with different morphologies grown by electrochemical deposition and their dye-sensitized solar cell properties
Authors:Min Zi  Min Zhu  Ling Chen  Haoming Wei  Xiaopeng Yang  Bingqiang Cao
Affiliation:1. School of Material Science and Engineering, Key Lab of Inorganic Functional Material in Universities of Shandong, University of Jinan, Jinan 250022, China;2. Shandong Provincial Key Lab of Preparation and Measurement of Building Materials, University of Jinan, Jinan 250022, China;3. Institut für Experimentelle Physik II, Universität Leipzig, Linnéstraße 5, D-04103 Leipzig, Germany
Abstract:
In this article, we grew zinc oxide (ZnO) samples with different morphologies, e.g. film, nanowire and nanosheet, with electrochemical deposition (ECD) by controlling the precursor concentration and the growth mechanism was also discussed. The morphology influence on the photovoltaic conversion efficiency of the dye-sensitized solar cells (DSSC) assembled with different ZnO photoanodes was investigated by measuring current density–voltage (JV) curve, quantum efficiency (QE) spectrum and electrochemical impedance spectrum (EIS). It was found that the DSSC constructed with ZnO nanowire array as photoanode can absorb more dye, improve the photon utilization rate and provide rapid collection channels for the photoexcited carriers. Therefore, the photovoltaic conversion efficiency of ZnO nanowire DSSC was improved.
Keywords:D. ZnO   Electrochemical deposition   Morphology of photoanodes   Dye-sensitized solar cell
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