Reductive Amination of Carbonyl Compounds over Silica Supported Palladium Exchanged Molybdophosphoric Acid Catalysts |
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Authors: | A Srivani P S Sai Prasad N Lingaiah |
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Affiliation: | (1) Catalysis Laboratory, Inorganic and Physical Chemistry Division, Indian Institute of Chemical Technology, Hyderabad, 500 607, India; |
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Abstract: | Abstract Palladium exchanged molybdophosphoric acid supported on silica is reported as a highly effective catalyst for direct reductive
amination of carbonyl compounds. The catalysts are characterized by X-ray diffraction and FT-infrared spectroscopy. The characterization
results support the existence of Keggin ion of heteropoly molybdate on silica. The catalyst is facile, water tolerable and
environmentally benign for reductive amination. A variety of secondary and tertiary amines can be synthesized over this catalyst
in excellent yields under mild reaction conditions. A plausible reaction mechanism is proposed for the reductive amination
of carbonyl compounds over this catalyst. |
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