| 季铵盐型二醋酸碘苯的合成及其氧化反应研究 |
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| 引用本文： | 郑兴良,罗丹,高鸿盛,丁爱顺,湛雪辉.季铵盐型二醋酸碘苯的合成及其氧化反应研究[J].广州化工,2011(3):76-77,100. |
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| 作者姓名： | 郑兴良 罗丹 高鸿盛 丁爱顺 湛雪辉 |
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| 作者单位： | 长沙理工大学化学与生物工程学院,湖南长沙,410114 |
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| 摘 要： | 以对碘苯甲醛为起始原料,经还原、卤代、季铵化、氧化反应,成功合成了具有季铵盐结构的二醋酸碘苯,考察了这种新型的二醋酸碘苯对醇的氧化反应,这种二醋酸碘苯的合成简单,反应条件温和,收率较高,对醇的氧化具有产率高,条件温和,选择性较好等优点。
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| 关 键 词： | 二醋酸碘苯 合成 氧化 |
Synthesis of Diacetoxyiodoarene with Quarter Amine Group and its Oxidization for Alcohols |
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| ZHENG Xing-liang,LUO Dan,GAO Hong-sheng,DING Ai-shun,ZHAN Xue-hui.Synthesis of Diacetoxyiodoarene with Quarter Amine Group and its Oxidization for Alcohols[J].GuangZhou Chemical Industry and Technology,2011(3):76-77,100. |
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| Authors: | ZHENG Xing-liang LUO Dan GAO Hong-sheng DING Ai-shun ZHAN Xue-hui |
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| Affiliation: | (College of Chemistry and Biologic Engineering,Changsha University of Science &Technology,Hunan Changsha 410114,China) |
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| Abstract: | Used 4-Iodobenzoaldehyde as the starting material,via reducing,conversion from 4-iodobenzyl alcohol to 4-iodobenyl chloride and forming quaternary ammonium salt,then oxiding quaternary ammonium salt,the diacetoxyiodobenzyl triethyl ammonium chloride was obtained successful in simple reactions,facile conditions and high yield.The oxidation of alcohols in diacetoxyiodobenzyl triethyl ammonium chloride was used as oxidant.Alcohols was oxidized by diacetoxyiodobenzyl triethyl ammonium chloride to afford aldehydes or ketones in high yields and good selectivity under mild condition. |
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| Keywords: | diacetoxyiodoarene synthesis oxidization |
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