A new route to functional polymers: Synthesis of functional polymer-supported esters from a weak acid ion exchange resin |
| |
| Affiliation: | 1. Department of Chemistry, University of Manchester, Oxford Road, Manchester M13 9PL, United Kingdom;2. Department of Chemistry, University of Lancaster, Bailrigg, Lancaster LA1 4YA, United Kingdom;1. WestCHEM, Department of Pure and Applied Chemistry, University of Strathclyde;1. Textile Engineering Department, Amirkabir University of Technology, Tehran, Iran;2. Chemical Engineering Department, Amirkabir University of Technology, Tehran, Iran;1. Smart Polymers and Nanocomposites Research Group, School of Chemical Engineering, Iran University of Science and Technology (IUST), Tehran 16846-13114, Iran;2. Molecular Simulation Research Lab, Department of Chemistry, Iran University of Science and Technology (IUST), Tehran 16846-13114, Iran |
| |
| Abstract: | Treatment of Amberlite IRC-50, a weak acid cation exchange resin containing methacrylic acid residues, with tetra-n-butylammonium hydroxide or benzyltrimethylammonium hydroxide gives the corresponding polymer-supported quaternary ammonium salts. These react smoothly, in nucleophilic substitution reactions, with a range of alkyl halides or sulfonates to give side chain esters with saturated hydrocarbon groups, with quaternary ammonium or sulfonate salt groups, with halide or alcohol groups at the terminus of spacer chains, with 1,2-diol groups, with acetylenic groups or with anthracene residues. These polymer-supported species have a variety of potential applications. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
