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Highlights during the development of electrochemical engineering
Authors:S. Bebelis,K. Bouzek,A. Cornell,M.G.S. Ferreira,G.H. Kelsall,F. Lapicque,C. Ponce de Leó  n,M.A. Rodrigo,F.C. Walsh
Affiliation:1. Department of Chemical Engineering, University of Patras, 1 Caratheodory Str.-University Campus GR 26504 Patras, Greece;2. Institute of Chemical Technology Prague, Department of Inorganic Technology, Technická 5, 166 28 Prague 6, Czech Republic;3. Applied Electrochemistry, School of Chemical Science and Engineering, KTH Royal Institute of Technology, SE-100 44 Stockholm, Sweden;4. Departamento de Engenharia de Materiais e Cerâmica, Universidade de Aveiro, 3810-193 Aveiro, Portugal;5. Department of Chemical Engineering, Imperial College London, London SW7 2AZ, UK;6. Laboratoire Réactions et Génie des Procédés, CNRS-Université de Lorraine, ENSIC BP 20451 F-54001 Nancy, France;g Electrochemical Engineering Laboratory, Energy Technology Research Group, Engineering Sciences, University of Southampton, University Road, Southampton SO17 1BJ, UK;h Departamento de Ingeniería Química, Facultad de Ciencias y Tecnologías Químicas, Universidad de Castilla-La Mancha, Edificio Enrique Costa Novella, Campus Universitario s/n, 13071 Ciudad Real, Spain
Abstract:Over the last century, electrochemical engineering has contributed significantly to societal progress by enabling development of industrial processes for manufacturing chemicals, such as chlorine and the Nylon precursor adiponitrile, as well as a wide range of metals including aluminium and zinc. In 2011, ca. 17 M tonne Cu p.a. was electro-refined to 99.99%+ purity required by electrical and electronic engineering applications, such as for electrodepositing with exquisite resolution multi-layer inter-connections in microprocessors. Surface engineering is widely practised industrially e.g. to protect steels against corrosion e.g. by electroplating nickel or using more recent novel self-healing coatings. Complex shapes of hard alloys that are difficult to machine can be fabricated by selective dissolution in electrochemical machining processes. Electric fields can be used to drive desalination of brackish water for urban supplies and irrigation by electrodialysis with ion-permeable membranes; such fields can also be used in electrokinetic soil remediation processes. Rising concerns about the consequences of CO2 emissions has led to the rapidly increasing development and deployment of renewable energy systems, the intermittency of which can be mitigated by energy storage in e.g. redox flow batteries for stationary storage and novel lithium batteries with increased specific energies for powering electric vehicles, or when economically viable, in electrolyser-fuel cells. The interface between electrochemical technology and biotechnology is also developing rapidly, with applications such as microbial fuel cells.
Keywords:Electrochemical engineering   Aluminium   Chlorate   Chlorine   Environmental electrochemistry   Fuel cells   Batteries   Corrosion
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