| [C3N5H4NH3]4XMo12O40(X=Si,Ge)荷移盐的合成与表征 |
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| 引用本文： | 周端文,刘喜正,程冬梅,殷利美.[C3N5H4NH3]4XMo12O40(X=Si,Ge)荷移盐的合成与表征[J].吉林化工学院学报,2006,23(4):6-7. |
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| 作者姓名： | 周端文 刘喜正 程冬梅 殷利美 |
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| 作者单位： | 吉林化工学院,制药与应用化学系,吉林,吉林,132073;吉林省伊通县计量局,吉林,伊通,130000 |
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| 摘 要： | 合成了二种新型杂多酸荷移盐(C3N5H4NH3)4SiMo12O401和(C3N5H4NH3)4GeMo12O402.并用元素分析、红外光谱对其进行表征.对化合物1和2的结构分析表明,化合物中的多阴离子仍保留着其Keggin结构,但其特征振动谱带有一定的红移或蓝移.结果表明,形成电荷转移盐之后的杂多阴离子是一个独立的单元,它通过静电引力与C3N5H4NH3+作用.
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| 关 键 词： | 多金属氧酸盐 Keggin结构 电荷转移化合物 |
| 文章编号： | 1007-2853（2006）04-0006-02 |
| 收稿时间： | 2006-06-26 |
| 修稿时间： | 2006年6月26日 |
Synthesis and characterizations of [ C3N5H4NH3 ]4XMo12O40( X = Yi, Ge) |
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| ZHOU Duan-wen,LIU Xi-zheng,CHEN Dong-mei,YIN Li-mei.Synthesis and characterizations of [ C3N5H4NH3 ]4XMo12O40( X = Yi, Ge)[J].Journal of Jilin Institute of Chemical Technology,2006,23(4):6-7. |
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| Authors: | ZHOU Duan-wen LIU Xi-zheng CHEN Dong-mei YIN Li-mei |
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| Abstract: | Two novel compounds C_3N_5H_4NH_3]_4XMo_(12)O_(40) No.1 and No.2 have been synthesized and characterized by means of IR spectrum and element analysis.The structural analysis of precipitation 1 and 2 suggested that heteropoly anions in these compounds still reserve their Keggin structures,but the characteristic vibration bands have some red shift or blue shift.The results show that the stronger interactions and charge transfer existing donor and acceptor. |
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| Keywords: | polyoxometalate Keggin structure charge transfer salts |
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