Effect of Heat Treatment Time on Dy–Cu Alloy Diffusion Process in Dy-Containing Commercial Nd–Fe–B Sintered Magnets

In this paper, the grain boundary diffusion process(GBDP) using a Dy_(70)Cu_(30)(at.%) alloy as the diffusion source was performed in a commercial sintered Nd–Fe–B magnet, and the effect of heat treatment time on the microstructure and magnetic properties of the magnet was investigated in detail. For the processed magnets heat-treated at 860℃, as heat treatment time increased, the coercivity and the depth of(Nd,Dy)_2Fe_(14)B core–shell structure increased first and then decreased. However, when the heat treatment time was more than 2 h, the diffusion path of Dy from the Dy-rich shell phase into the Nd_2Fe_(14)B grains was revealed, and a nearly homogeneous(Nd,Dy)_2Fe_(14)B phase was formed, which brought on the decrease in both the depth of visible core–shell structure and the coercivity of Nd–Fe–B magnet.

Effect of Heat Treatment Time on Dy-Cu Alloy Diffusion Process in Dy-Containing Commercial Nd-Fe-B Sintered Magnets

In this paper, the grain boundary diffusion process (GBDP) using a Dy₇₀Cu₃₀ (at.%) alloy as the diffusion source was performed in a commercial sintered Nd-Fe-B magnet, and the effect of heat treatment time on the microstructure and magnetic properties of the magnet was investigated in detail. For the processed magnets heat-treated at 860 °C, as heat treatment time increased, the coercivity and the depth of (Nd,Dy)₂Fe₁₄B core-shell structure increased first and then decreased. However, when the heat treatment time was more than 2 h, the diffusion path of Dy from the Dy-rich shell phase into the Nd₂Fe₁₄B grains was revealed, and a nearly homogeneous (Nd,Dy)₂Fe₁₄B phase was formed, which brought on the decrease in both the depth of visible core-shell structure and the coercivity of Nd-Fe-B magnet.