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NH_3-CO_2-H_2O体系热力学汽液平衡计算应用
引用本文:张香平,袁一,詹世亮,姚平经.NH_3-CO_2-H_2O体系热力学汽液平衡计算应用[J].化学工程,2002,30(2):64-67.
作者姓名:张香平  袁一  詹世亮  姚平经
作者单位:大连理工大学,化工学院,辽宁,大连,116012
摘    要:基于Edwards模型对NH3 CO2 H2 O体系进行了热力学平衡模拟计算 ,开发了在较稀浓度范围内收敛性较好的计算程序 ,所得计算结果与文献实验数据的偏差在允许范围之内。对尿素流程冷凝工段的闪蒸过程进行了模拟计算 ,结果同实验数据及设计数据吻合较好。

关 键 词:NH3CO2H2O体系  相平衡  模拟计算  尿素生产流程
文章编号:1005-9954(2002)02-0064-04

Thermodynamic Equilibrium Calculation and Application of the NH3-CO2-H2O System
ZHANG Xiang ping,YUAN Yi,ZHAN Shi liang,YAO Ping jing.Thermodynamic Equilibrium Calculation and Application of the NH3-CO2-H2O System[J].Chemical Engineering,2002,30(2):64-67.
Authors:ZHANG Xiang ping  YUAN Yi  ZHAN Shi liang  YAO Ping jing
Abstract:Based on the Edwards′ thermodynamic model,the program of simulation calculation has been developed for NH 3 CO 2 H 2O solution.The comparison with literature data reveals a good agreement.This program has been applied for calculating the phase equilibrium of the condensers in the urea process successfully.The calculated results agreed well with the design values.
Keywords:ammonia  carbon dioxide  water system  phase equilibrium  simulation  urea process  
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