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Anhydrous esterification of myristic acid with propylene: Ion exchange resin and acid-treated clay as catalysts
Authors:Animesh Chakrabarti  Man Mohan Sharma
Affiliation:(1) University Department of Chemical Technology, University of Bombay, Matunga, 400 019 Bombay, India
Abstract:Anhydrous esterification of myristic acid with propylene was carried out in the temperature range of 110–145°C and pressure from 190–195 psig in the presence of Amberlyst-15 (cation exchange resin) and Filtrol-24 (acid-treated clay) as catalysts. The product ester, isopropyl myristate finds use in cosmetic and topical medicinal preparations where good absorption through the skin is desired. Filtrol-24 is the catalyst of choice, and the recommended operating temperature is 130°C with a pressure of 190 psig.
Keywords:Acid-treated clay  cation exchange resin  isopropyl myristate  myristic acid  propylene
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