| 直接甲酸燃料电池阳极催化剂的研究进展 |
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| 引用本文： | 徐群杰,周小金,李巧霞,李金光.直接甲酸燃料电池阳极催化剂的研究进展[J].上海电力学院学报,2009,25(5):453-456. |
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| 作者姓名： | 徐群杰 周小金 李巧霞 李金光 |
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| 作者单位： | 上海电力学院,能源与环境工程学院,上海,200090 |
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| 基金项目： | 上海市教委科技创新重点项目，上海市教委科技创新一般项目，上海电力学院研究生创新基金项目 |
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| 摘 要： | 介绍了直接甲酸燃料电池（DFAFC）阳极电催化机理,以及Pt基、Pd基附载型和非附载型阳极催化剂的发展状况,分析了金属合金d-带能级移动和金属表面偏析对直接甲酸燃料电池催化活性的影响,对筛选阳极催化剂合金材料具有一定的指导作用.
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| 关 键 词： | 直接甲酸燃料电池 阳极催化剂 电催化 d-带移动 表面偏析 |
| 收稿时间： | 2009/6/30 0:00:00 |
Development of Anode Catalyst for Direct Formic Acid Fuel Cells |
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| XU Qun-jie,ZHOU Xiao-jin,LI Qiao-xia and LI Jin-guang.Development of Anode Catalyst for Direct Formic Acid Fuel Cells[J].Journal of Shanghai University of Electric Power,2009,25(5):453-456. |
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| Authors: | XU Qun-jie ZHOU Xiao-jin LI Qiao-xia and LI Jin-guang |
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| Affiliation: | ( School of Thermal Power and Environmental Engineering, Shanghai University of Electric Power, Shanghai 200090, China) |
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| Abstract: | The mechanism of the catalysts for electro-oxidation of formic acid is introduced, as well as the recent advances of the supported/unsupported Pt-based/Pd-based anode materials and the influence of the d-band shift and metal surface segregation to the catalytic activity are analyzed, providing guidance of filtering the potential candidates of the new alloy anode materials. |
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| Keywords: | direct formic acid full cells anode catalysts electro-catalysis d-band shift surfacesegregation |
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