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The Zn-rich corner of the 450 °C isothermal section of the Zn–Bi–Fe–Ni quaternary system
Authors:Chunmei Liu  Jianhua Wang  Fucheng Yin  Zhi Li  Xuping Su  
Affiliation:aKey Laboratory of Materials Design and Preparation Technology of Hunan Province, School of Mechanical Engineering, Xiangtan University, Hunan, PR China
Abstract:Following up on recent studies of the isothermal section of the Zn–Fe–Ni, Zn–Fe–Bi and Zn–Bi–Ni ternary systems at 450 °C, the Zn-rich corner of the 450 °C isothermal section of the Zn–Bi–Fe–Ni quaternary system with the Zn being fixed at 93 at.% was determined experimentally using the equilibrated alloys approach. The specimens were investigated by means of scanning electron microscopy (SEM) equipped with energy dispersive X-ray spectroscopy (EDS), and X-ray diffraction (XRD). It was found there exist 4 two-phase regions, 5 three-phase regions and 2 four-phase regions. Two liquid L (Zn) and L (Bi) can coexist with T, ζ and δ-Ni in this isothermal section, no new phase was found in this study.
Keywords:Zn–  Bi–  Fe–  Ni  Phase diagram  Zn–  base alloy
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