Synthesis of polyurethane graft copolymers by polyaddition reaction of dihydroxyl-terminated macromonomers |
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Authors: | Yoshiki Chujo Tokuo Tatsuda Yuya Yamashita |
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Affiliation: | (1) Department of Synthetic Chemistry, Faculty of Engineering, Nagoya University, Furo-cho, Chikusa-ku, 464 Nagoya, Japan |
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Abstract: | Summary Polyurethane-poly(methyl methacrylate) graft copolymers of well-defined structure and composition were synthesized by macromonomer method. Dihydroxyl-terminated macromonomer was prepared by radical polymerization of methyl methacrylate in the presence of -thioglycerol as a chain transfer agent. This dihydroxyl-terminated macromonomer and 1,4-butanediol were added to diisocyanate (hexamethylene diisocyanate or toluene-2,4-diisocyanate) catalyzed by di-n-butyltin dilaurate to produce tailor-made graft copolymers. |
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