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煤泥水煤浆燃烧特性的热重研究
引用本文:曹晓哲,赵卫东,刘建忠,孙剑峰,周俊虎,岑可法.煤泥水煤浆燃烧特性的热重研究[J].煤炭学报,2009,34(10):1394-1399.
作者姓名:曹晓哲  赵卫东  刘建忠  孙剑峰  周俊虎  岑可法
作者单位:浙江大学 能源清洁利用国家重点实验室,浙江 杭州,310027
摘    要:采用热重分析仪研究了山西潞安煤泥水煤浆的着火、燃烧特性,并与不同低挥发分含量的水煤浆进行了对比;利用TG-DTG法确定了燃烧的着火和燃尽温度,利用Coats-Redfern法进行反应动力学分析.试验结果表明:潞安煤泥水煤浆的着火温度和燃尽温度均高于低挥发分和高挥发分水煤浆,利用可燃性指数判断潞安煤泥水煤浆燃烧性能低于低挥发分和高挥发分水煤浆.由燃烧反应动力学分析结果表明:在不同的升温速率下(12.5,33.3,50.0 ℃/min),潞安煤泥水煤浆的活化能指数(120.89,7850,71.48 kJ/mol)均高于低挥发分和高挥发分水煤浆.

关 键 词:煤泥  水煤浆  燃烧特性  热重分析  动力学分析  
收稿时间:2008-11-18

A thermogravimetry investigation on the combustibility of coalslime water slurry
Abstract:The ignition and combustion characteristics of Lu’an coalslime water slurry (CWS) were studied through thermogravimetric apparatus, and its combustibility was compared with that of the coal water slurry samples made by a low volatile matter coal and a high volatile matter coal. The ignition and burnout temperature was obtained by TG-DTG method, and the reaction kinetics were analysed with Coats Redfern method.  The results show that the ligniton and burnout temperatures of Lu’an coalslime water slurry are higher than that of low volatile matter CWS and high volatile matter CWS; the combustibility of Lu’an coalslime water slurry is worse than that of low volatile matter CWS and high volatile matter CWS by using signitability number. The dynamic analysis shows that at different conversion rate(12.5, 33.3, 50.0 ℃/min), activation energy E(120.89,7850,71.48 kJ/mol), Lu’an coalslime water slurry is higher than that of low volatile matter CWS and high volatile matter CWS.
Keywords:coalslime  coal water slurry(CWS)     combustibility  thermogravimetry  dynamic analysis
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