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Anodic oxidation of some phenols related to lignin — II. Oxidation of isoeugenol methylether and 4-propylveratrole in acetonitrile
Authors:Bernard Chabaud  Franciska Sundholm  Göran Sundholm
Affiliation:Département de Recherche Fondamentale, Centre d''Etudes Nucléaires de Grenoble, BP 85, Centre de Tri, 38041 Grenoble, France;Department of Chemistry, Helsinki University, Et. Hesperiank, 4, 00100 Helsinki 10, Finland;Department of Chemistry, Helsinki University of Technology, 02150 Espoo 15, Finland
Abstract:
The anodic oxidation of isoeugenol methylether and 4-propylveratrole has been studied in unbuffered acetonitrile solution and in solutions buffered with pyridine and 2,6-lutidine using cyclic voltammetry, steady-state measurements on rotating electrodes, coulometry, esr, uv-spectroscopy, nonlinear galvanostatics and preparative electrolysis. Reaction mechanism, which account for the experimental results, are presented and discussed.
Keywords:To whom correspondence should be addressed.
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