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Microstructure and phase composition of cordierite-based co-clinker
Authors:Abdel Monem Mohamed Soltan  Hassan Elshimy  Fawzia Abd EL-Raoof  Florian Fuchs  Andreas Köenig  Ahmed Mohamed Yahya  Mohamed Mostafa AbdelFattah  Mohamed Serry  Herbert Pöllmann
Affiliation:1. Geology Department, Faculty of Science, Ain Shams University, Cairo 11566, Egypt;2. Physics Department, Faculty of Science, Ain Shams University, Cairo 11566, Egypt;3. Ceramic Department, National Research Center, Dokki, Cairo 12622, Egypt;4. Institute of Materials Science, Leipzig University, Leipzig D-04275, Germany;5. Geology Department, Institute of Geology and Geography, Martin-Luther University, Von Seckendorff-Platz 3, Halle (Saale) 06120, Germany
Abstract:The aim of this work is to study the effect of phase composition and microstructure of cordierite-based co-clinkers on the electrical properties and coefficient of thermal expansion of cordierite briquettes. To achieve this aim talc and kaolinite samples were collected from quarries in the Egyptian desert. The samples are characterized using XRD, XRF, polarized light, cathodoluminescence and SEM microscopy attached with EDAX, in addition to X-ray micro-computed tomography (3D- µXCT). The electrical properties and coefficient of thermal expansion of the cordierite briquettes are determined using HiTESTER instrument and automatic Netzsch DIL402 PC dilatometer, respectively.Five talc-based batches were shaped and fired in the temperature range 1000–1350 °C for 2 h. The microstructural and physical characteristics of the resulted cordierite-based co-clinkers depend mainly on the viscosity of the liquid phase developed during firing. The microchemistry of the cordierite briquettes confirms their enrichment of both cordierite and ferroan-cordierite crystallized directly from locally developed melts. The dielectric constant and loss factor values for cordierite briquettes allow their possible use as insulator components in electronic applications.
Keywords:Talc  Cordierite  Microstructure  Tomography  Ceramics
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