Synthesis, structure and catalytic activities for the hydrogen transfer reactions of the ruthenium(II) carbonyl chloride complexes with pyridine-2,6-diimine |
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| Authors: | Xiang-Yong Lu Hui-Jun Xu Xue-Tai Chen |
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| Affiliation: | aState Key Laboratory of Coordination Chemistry, Nanjing National Laboratory of Microstructures, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, PR China |
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| Abstract: | Two Ru(II) carbonyl chloride complexes with pyridine-2,6-diimine, (L)Ru(CO)Cl2 (L = 2,6-diacetylpyridinebis(2,4,6-trimethylanil), 1; L = 2,6-diacetylpyridinebis(2,6-diisopropylanil), 2) have been synthesized and characterized. The structure of compound 1 has been determined by X-ray crystallography, which show the distorted octahedral geometry around Ru(II). Complexes 1 and 2 have been proved to be active in the transfer hydrogenation of acetophenone by propan-2-ol. |
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| Keywords: | Ruthenium complex Crystal structure Transfer hydrogenation Pyridine-2,6-diimine |
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