| SO42-/TiO2-La2O3催化合成丙酸丁酯 |
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| 引用本文： | 杨水金,童文龙,李福宝.SO42-/TiO2-La2O3催化合成丙酸丁酯[J].精细石油化工进展,2004,5(3):12-14. |
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| 作者姓名： | 杨水金 童文龙 李福宝 |
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| 作者单位： | 湖北师范学院化学与环境工程系,黄石,435002 |
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| 基金项目： | 湖北省教育厅重点科研基金(2002A00008)资助项目. |
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| 摘 要： | 首次以稀土改性的固体超强酸SO4^2-／TiO2-La2O3为催化剂，通过丙酸和正丁醇反应合成丙酸丁酯，并探讨了诸因素对酯收率的影响。在醇酸摩尔比1．2：1，催化剂用量占反应物料总量的2．5％，反应时间1．5h，反应温度94-110℃的条件下，酯收率可达83．6％。SO4^2-／TiO2-La2O3具有良好的催化活性。
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| 关 键 词： | SO4^2-／TiO2-La2O3 催化合成技术 丙酸丁酯 固体超强酸 酯化反应 |
| 修稿时间： | 2003年11月6日 |
Synthesis of n - Butyl Propionate Catalyzed by SO42-/TiO2- La2O3 |
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| Yang Shuijin Tong Wenlong Li Fubao.Synthesis of n - Butyl Propionate Catalyzed by SO42-/TiO2- La2O3[J].Advances in Fine Petrochemicals,2004,5(3):12-14. |
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| Authors: | Yang Shuijin Tong Wenlong Li Fubao |
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| Abstract: | n-Butyl propionate was synthesized from n-butanol alcohol and propionic acid in the presence of SO42-/TiO2-La2O3.The factors influencing the synthesis were discussed and the best conditions were determined. The optimum conditions are as follows: molar ratio of n-butanol alcohol to propionic acid is 1 .2 :1, the quantity of catalyst is equal to 2.5% of feed stocks,and the reaction time 1.5 h.SO42-/TiO2-La2O3 is an excellent catalyst for synthesizing n-butyl propionate and its yield can reach over 83.6 % . |
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| Keywords: | n-butyl propionate solid superacid rare earth catalysis esterification |
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