Micro-printing performance of durable water-repellent black polyester-spandex fabrics without fluorine and silicone resins北大核心CSCD

Synthetic fibers are widely used because of their stable chemical properties high mechanical strength and low cost. Among them polyester has the largest production and is the most widely used and China is also the country with the largest polyester production in the world. With the technological progress of energy saving and emission reduction of liquid disperse dyes the technology of micro printing of polyester and polyester / spandex fabrics has been realized. Based on the high market share of black polyester / spandex printed fabrics and the increasing market demand for functional finishing (e. g. anti-static finishing water repellent finishing UV resistance finishing etc.), it is of great significance to study the process of one-step short processing of polyester printing and functional finishing using carbon-based materials (e. g. carbon black). Carbon black is a gray-black organic pigment with good antistatic and anti-UV properties. It is an eco-friendly advanced material that integrates printing dyeing and functional finishing. To make up for the lack of color depth of carbon black pigment a disperse black dye and carbon black pigment in the same bath preparation scheme are chosen to prepare a functional liquid carbon black @ disperse black dye (CB-D). Not only does CB-D meet the requirements of deep black printing but also it can simultaneously provide water-repellent finishing to the fabric. In this way the application of organic fluorine or organic silicon resin can be dispensed with. A functional liquid CB-D was prepared by pre-dispersion and zirconium oxide grinding method under the action of abrasive agent AL50 (anionic / non-ionic surfactant complex) . The effects of CB-D mass fraction binder type binder D101 mass fraction baking temperature and time on color (L? value) rubbing and soaping colorfastness were investigated by optimizing the printing process of liquid CB-D. At the same time the fixation mechanism of CB-D was investigated and the properties of polyester-spandex printed fabrics were tested. The stability of CB-D and the colorfastness of polyester-spandex printed fabrics to hot-wash effluent were investigated by the rate of change of absorbance. The effect of hot-washing on dye floating in the printed area and dye staining in the non-printed area was characterized by the brightness of the printed area L? value and the whiteness of the non-printed area (CIE whiteness W10). The properties of CB-D were characterized by scanning electron microscopy and transmission electron microscopy and the antistatic property water repellency air permeability moisture permeability and tensile breaking strength of the fabrics were tested. (i) The first functional liquid CB-D with excellent stability is prepared by grinding carbon black and disperse black dye composed of orange 288 purple 93 and blue 291:3 in the same bath. (ii) A durable fluorine-free and silicone-free water repellent black polyester spandex fabric is prepared reducing the cost of functional finishing and environmental pollution. The preparation of durable water-repellent polyester spandex fabrics without a functional finishing agent is a new technology. CB-D as functional organic melanin with excellent performance and simple processing is a new low-carbon and eco-friendly material and ecological printing and dyeing process. (i) As for the black polyester spandex fabric prepared by a micro-printing process the color fastness of deep black color is not less than grade 4 the white ground is not stained and the color of wastewater is very low. The printing process requires 5% functional CB-D and 8. 5% binder D101. (ii) The black polyester spandex fabric has excellent and durable water repellency air permeability moisture permeability and antistatic property. The water contact angle is 132° anti-static grade is A and the air permeability and moisture permeability are more than 260 mm / s and 2 880 g / (m2h) respectively. After 30 times of home washing it almost keeps the original excellent performance. (iii) The CB-D prepared based on carbon black and disperse black dye is a colloidal aggregate that easily forms continuous carbon black aggregates on the fiber surface showing more excellent porosity film formation and water repellency while maintaining air permeability and moisture permeability. Carbon black is a low-cost material and the liquid CB-D prepared by modifying carbon black with disperse black dye has a new use in preparing functional textiles with good application prospects. © 2022 Authors. All rights reserved.