| 钯/竹炭催化剂的制备及表征 |
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| 引用本文： | 曾韬,杨彦春.钯/竹炭催化剂的制备及表征[J].生物质化学工程,2008,42(5):25-29. |
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| 作者姓名： | 曾韬 杨彦春 |
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| 作者单位： | 南京林业大学 化学工程学院, 江苏 南京 210037 |
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| 基金项目： | 国家自然科学基金，国家林业局公益性行业科研专项 |
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| 摘 要： | 采用H2O2和HClO4对竹炭进行改性,并用氧化负载法(以H2O2和 NaClO 为氧化剂)改进金属钯在载体竹炭上的负载,制备出钯/竹炭催化剂(Pd/BC)。经对湿地松松香的歧化反应试验,并与市售钯/炭(Pd/C)催化剂比较,结果表明,以H2O2和HClO4体积比1:1混合溶液改性竹炭,并以H2O2和NaClO体积比5:1混合氧化剂负载钯所得Pd/BC-17催化剂具有较高的催化活性,催化活性优于含钯量 5% 的市售Pd/C催化剂。
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| 关 键 词： | 竹炭 钯/竹炭催化剂 制备 表征 |
| 收稿时间： | 2008-03-10 |
Preparation and Characterization of Palladium/Bamboo-charcoal (Pd/BC) Catalyst |
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| ZENG Tao,YANG Yan-chun.Preparation and Characterization of Palladium/Bamboo-charcoal (Pd/BC) Catalyst[J].Biomass Chemical Engineering,2008,42(5):25-29. |
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| Authors: | ZENG Tao YANG Yan-chun |
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| Affiliation: | College of Chemical Engineering, Nanjing Forestry University, Nanjing 210037, China |
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| Abstract: | The Pd/BC catalyst was prepared through improving the loading process and modifying the bamboo charcoal. The optimal condition is the volume ratio of H2O2 to HClO4 is 1:1 in modifying process, the volume ratio of H2O2 to NaClO is 5:1 in oxidation loading process. The activity of Pd/BC catalyst is better than that of commercial product which has palladium content of 5%. |
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| Keywords: | bamboo charcoal Pd/BC catalyst preparation characterization |
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