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Catalytic Partial Oxidation of n-Heptane for Hydrogen Production
Authors:Ran Ran  Guoxing Xiong  Shishan Sheng  Weishen Yang  Norbert Stroh  Herwig Brunner
Affiliation:(1) State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, P.O. Box 110, Dalian, 116023, China;(2) Fraunhofer Institute for Interfacial Engineering and Biotechnology, Nobelstrasse 12, D-70569 Stuttgart, Germany
Abstract:Partial oxidation of n-heptane (POH) for hydrogen generation was studied over several catalysts between 700 and 850 °C. Modified Ni-based/gamma-Al2O3 catalyst exhibited not only good catalytic activity but also good carbon deposition resistance ability. Under the modified reaction conditions, 100% n-heptane conversion and 93% hydrogen selectivity can be obtained.
Keywords:partial oxidation  n-heptane  Ni-based catalyst  hydrogen production  carbon deposition
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