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含不同钾盐消焰剂的NC/TMETN推进剂熄火表面特征研究
引用本文:陈沛,赵凤起,李上文. 含不同钾盐消焰剂的NC/TMETN推进剂熄火表面特征研究[J]. 火炸药学报, 2002, 25(3): 47-50,22
作者姓名:陈沛  赵凤起  李上文
作者单位:西安近代化学研究所,陕西,西安,710065;西安近代化学研究所,陕西,西安,710065;西安近代化学研究所,陕西,西安,710065
摘    要:利用扫描电镜(SEM)和能谱仪研究了含不同钾盐的NC/TMETN推进剂熄 火表面特征,研究结果表明,有机钾盐KD使用进剂熄火表面上Cu元素的含量降低,导致Pb和Cu的复合催化作用减弱,而KNO3使推进剂熄火表面碳含量降低,铅球尺寸增大,导致催化活性组分减少,催化作用减弱;K3AlF6与铅的氧化物在推进剂熄火表面形成了PbF4,从而完全破坏了铅化物的催化作用。

关 键 词:钾盐  NC/TMETN推进剂  熄火表面特征
文章编号:1007-7812(2002)03-0047-04

The Study on the Quenched Surface Characteristics of NC/TMETN Propellant with Potassium Salt
CHEN Pei,ZHAO Feng qi,LI Shang wen. The Study on the Quenched Surface Characteristics of NC/TMETN Propellant with Potassium Salt[J]. Chinese Journal of Explosives & Propellants, 2002, 25(3): 47-50,22
Authors:CHEN Pei  ZHAO Feng qi  LI Shang wen
Abstract:The quenched surface characteristics of NC/TMETN propellant with potassium salts were investigated by the scanning electron microscopy (SEM) and the LINK ISIS energy spectrum. The results showed that Cu content on the quenched surface reduced because of KD added into the NC/TMETN composition, which weak ened the cooperation between Pb and Cu. While the carbon content on the quenched surface depressed and the size of Pb ball increaied due to KNO 3, which lead the active materials to decrease and the catalysis to weaken. Because K 3AlF 6 reacted with the oxide of Pb to form PbF 4,the catalysis of Pb compound was destroyed completely.
Keywords:potassium salts  NC/TMETN propellant  characteristics of propellant quenched surface
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