Effect of the reaction time, reagent concentration and sample thickness on the thermal derivatisation of p porous silicon with α-undecene and ω-carboxy alkenes: A FTIR investigation

This paper presents a detailed study, based on Fourier transform infrared (FTIR) analysis, on the derivatisation of p⁺-type porous silicon (PS) via thermal activated hydrosilylation of α-undecene. The α-undecene was used as a model for alkene precursor to calculate the efficiency of the hydrosilylation reaction, determined by comparing the integrated intensity of the SiH_x peaks (2200–2000 cm⁻¹) of the as-prepared and modified sample, by varying three parameters: the reaction time, the reagent concentration and the sample thickness. This study aims to optimize the PS derivatisation as a function of the thickness, in order to consider the thermal activation as a useful process for modifying PS slab waveguide for sensing application. Moreover two methods using ω-carboxy alkenes (where the carboxylic moiety was an ester or an acid) to obtain a PS surface –COOH-terminated, to be exploited for bioconjugation protocols, were tested and the reactions efficiency compared with the alkene model, i.e. α-undecene. FTIR spectroscopy and contact angle measurements were used to characterize the modified PS samples.