Densification and Mechanical Properties of B4C with Al2O3 as a Sintering Aid

The densification behavior and mechanical properties of B₄C hot-pressed at 2000°C for 1 h with additions of Al₂O₃ up to 10 vol% were investigated. Sinterability was greatly improved by the addition of a small amount of Al₂O₃. The improvement was attributed to the enhanced mobility of elements through the Al₂O₃ near the melting temperature or a reaction product formed at the grain boundaries. As a result of this improvement in the density, mechanical properties, such as hardness, elastic modulus, strength, and fracture toughness, increased remarkably. However, when the amount of Al₂O₃ exceeded 5 vol%, the level of improvement in the mechanical properties, except for fracture toughness, was reduced presumably because of the high thermal mismatch between B₄C and Al₂O₃.