Large Electromechanical Strain in Lead‐Free Binary System K0.5Bi0.5TiO3‐Bi(Mg0.5Ti0.5)O3 |
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Authors: | Aurang Zeb Steven J Milne |
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Affiliation: | Institute for Materials Research, University of Leeds, , Leeds, LS2 9JT UK |
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Abstract: | Solid solution formation in the lead‐free binary system (1?x)K0.5Bi0.5TiO3?xBi(Mg0.5Ti0.5)O3 has been studied for compositions x ≤ 0.12. X‐ray powder diffraction shows single‐phase perovskite for x < 0.1, and a mixed phase region between tetragonal and pseudocubic phases for compositions 0.04 ≤ x ≤ 0.06. Large electromechanical strains of ~0.3% at fields of 50 kV/cm are recorded in the mixed phase region, with d33* (Smax/Emax) values of ~600 pm/V. The materials sustain polarization at low electric fields with remnant polarization ~18 μC/cm2 and coercive field ~20 kV/cm for x = 0.06. Relative permittivity‐temperature plots display relaxor characteristics, with peak temperature ~340°C. |
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