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Effect of MoSi2/rare earth composite particles on microstructure and mechanical properties of molybdenum
Authors:Xiuqi ZanDezhi Wang  Kaihua ShiAokui Sun  Bing Xu
Affiliation:
  • Key Laboratory of Nonferrous Metal Materials Science and Engineering, Ministry of Education, Changsha 410083, PR China
  • School of Materials Science and Engineering, Central South University, No. 932, Lushan Nanlu, Changsha 410083, PR China
  • Abstract:
    MoSi2/La2O3 and MoSi2/Y2O3 composite particles were prepared by mechanical milling and doped into molybdenum by solid-solid method, respectively. Rods with a diameter of 17 mm were made by pressing and sintering. The effects of different composite particles on microstructures and strength of the as-sintered molybdenum were investigated. Results show that the MoSi2/La2O3 and MoSi2/Y2O3 composite particles transformed to La2O3/Mo5Si3 and Y2O3/Mo5Si3 composite particles due to the in situ reaction between Mo and MoSi2 during sintering process. Mo5Si3/La2O3 and Mo5Si3/Y2O3 composite particles can reduce the grain size and improve both strength and toughness of sintered molybdenum significantly. Mo5Si3/Y2O3 composite particles contribute more to the strength, while the effect of Mo5Si3/La2O3 on toughness is greater than that of Mo5Si3/Y2O3.
    Keywords:MoSi2/rare earth   Sintered molybdenum   Microstructure   Property
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