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Impact strength elastomer composites based on polystyrene components separated from waste electrical and electronic equipment
Authors:Ramona M Grigorescu  Paul Ghioca  Lorena Iancu  Madalina E Grigore  Rodica-Mariana Ion  Cristian-Andi Nicolae  Raluca Gabor  Mircea I Filipescu  Maria Rapa  Roxana D Trusca  Marius Ghiurea
Affiliation:1. National Institute for Research & Development in Chemistry & Petrochemistry—ICECHIM, 202 Splaiul Independentei, 060021 Bucharest, Romania;2. National Institute for Research & Development in Chemistry & Petrochemistry—ICECHIM, 202 Splaiul Independentei, 060021 Bucharest, Romania

Institute of Multidisciplinary Research for Science and Technology, Valahia University of Târgoviste, 13 Aleea Sinaia, 130004 Târgoviste, Romania;3. Center of Research and Eco-Metallurgical Expertise, University Politehnica of Bucharest, 313 Splaiul Independentei, 060042 Bucharest, Romania;4. Faculty of Engineering in Foreign Languages, University Politehnica of Bucharest, 313 Splaiul Independentei, 060042 Bucharest, Romania

Abstract:The reuse of plastic components of waste electrical and electronic equipment (WEEE) is an important concern both for environmental issues and to preserve the material resources, with minimum energy consumption. Considering that polystyrene fraction was reported as approximate 80% of the total amount of WEEE plastic, this article aims to evaluate the recycling of this fraction, without separation by components, by melt compounding with styrene-butadiene block-copolymer (SBS) and hydrogenated and maleinized SBS, the blend of the two elastomers acting both as an impact modifier and compatibilizer. The composites are characterized by mechanical analysis, impact tests, dynamic mechanical analysis, differential scanning calorimetry, thermogravimetric analysis, scanning electron microscopy, energy dispersive X-ray analysis, and X-ray diffraction. The recycling conditions of the polystyrene fraction as composites without eliminating the WEEE additives for improved UV and flame resistance, with physical mechanical properties comparable to those of high-impact polystyrene resulted from the study. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2020 , 137, 48329.
Keywords:high impact polystyrene  melt compounding  polystyrene fraction from WEEE  SBS  SEBS-g-MA
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