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镁基储氢材料在含能材料中的应用
引用本文:陈曦,邹建新,曾小勤,丁文江.镁基储氢材料在含能材料中的应用[J].火炸药学报,2016(3):1-8.
作者姓名:陈曦  邹建新  曾小勤  丁文江
作者单位:1. 上海交通大学轻合金精密成型国家工程研究中心,上海,200240;2. 上海交通大学轻合金精密成型国家工程研究中心,上海200240; 上海交通大学金属基复合材料国家重点实验室,上海200240
基金项目:上海市基础重点项目(14JC1491600);上海交通大学-航天八院联合基金
摘    要:根据化学结构不同将镁基储氢材料分为镁基储氢合金氢化物、氢化镁和镁基配位氢化物3类,分别介绍了3类镁基储氢材料在含能材料中应用的研究进展;分析了镁基储氢材料在含能材料中的应用前景和存在的问题;介绍了计算机模拟技术在研究镁基储氢材料对推进剂热分解影响中的应用情况。结果显示,镁基储氢材料能够通过促进含能材料的热分解过程提升其能量水平,同时其较高的热稳定性有利于改善含能材料组分的相容性和安定性。镁基储氢合金氢化物、氢化镁和镁基配位氢化物均可显著提高固体推进剂和炸药的应用性能。因此,镁基储氢材料在含能材料领域具有广阔的应用前景。附参考文献47篇。

关 键 词:含能材料  镁基储氢材料  镁基储氢合金氢化物  氢化镁  镁基配位氢化物  固体推进剂

Applications of Mg-based Hydrogen Storage Materials in Energetic Materials
Abstract:According to the difference of chemical structure ,Mg‐based hydrogen storage materials were divided into three categories :Mg‐based hydrogen storage alloy hydrides ,MgH2 and Mg‐based metal complex hydrides .The research progress in the application of the three categories of Mg‐based hydrogen storage materials in energetic materials was introduced .The application prospects and existing problems of Mg‐based hydrogen storage materials in energetic materials were analyzed .The application situation of computer simulation technology in the study of Mgbased hydrogen storage materials affecting the thermal decomposition of propellant was introduced .The results reveal that Mg‐based hydrogen storage materials can promote the thermal decomposition process of energetic materials to improve their energy level and the relatively higher thermal stability of Mg‐based hydrogen storage materials enhances the compatibility and stability of energetic materials .Mg‐based hydrogen storage alloy hydrides ,MgH2 and Mg‐based metal complex hydrides can significantly improve the application performance of solid propellants and ex ‐ plosives .Therefore ,the Mg‐based hydrogen storage materials have broad application prospects in the field of energetic materials .With 47 references .
Keywords:energetic materials  Mg-based hydrogen storage materials  Mg-based hydrogen storage alloy hydrides  MgH2  Mg-based metal complex hydrides  solid propellant
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