| 几种Salen双肟类衍生物及其配合物的合成与表征 |
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| 引用本文： | 冯建华,葛秀涛,薛连海,郑建东,冯剑,侯金松.几种Salen双肟类衍生物及其配合物的合成与表征[J].应用化工,2011,40(3):414-416,419. |
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| 作者姓名： | 冯建华 葛秀涛 薛连海 郑建东 冯剑 侯金松 |
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| 作者单位： | 滁州学院,化学与生命科学系,安徽滁州,239000 |
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| 基金项目： | 2010年安徽省高等学校优秀青年人才基金项目，2010年安徽省教育厅自然科学研究基金项目，安徽省应用化学省级重点学科建设项目 |
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| 摘 要： | 以12,-二胺氧乙烷、1,3-二胺氧丙烷、1,4-二胺氧丁烷及3种水杨醛衍生物为原料,以无水乙醇为溶剂,在常压、55℃条件下合成了9种新型的Salen双肟类衍生物,与过渡金属盐类作用制备了其配合物。用元素分析、红外光谱、核磁共振及差热-热重等测试技术对化合物的结构进行了表征。结果表明,所合成的新型Salen双肟类衍生物均为四齿含氮配体并与过渡金属离子有较强的配位能力,反应条件温和,收率较高。
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| 关 键 词： | salen型双肟配体 配合物 合成 表征 |
Synthesis and characterization of novel salen-type bisoxime derivatives and their complexes |
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| FENG Jian-hua,GE Xiu-tao,XUE Lian-hai,ZHENG Jian-dong,FENG Jian,HOU Jin-song.Synthesis and characterization of novel salen-type bisoxime derivatives and their complexes[J].Applied chemical industry,2011,40(3):414-416,419. |
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| Authors: | FENG Jian-hua GE Xiu-tao XUE Lian-hai ZHENG Jian-dong FENG Jian HOU Jin-song |
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| Affiliation: | FENG Jian-hua,GE Xiu-tao,XUE Lian-hai,ZHENG Jian-dong,FENG Jian,HOU Jin-song(Department of Chemistry and Life Science,Chuzhou University,Chuzhou 239000,China) |
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| Abstract: | Nine kinds of novel salen-type bisoxime derivatives were synthesized at atmosphere,55 ℃ from self-made 1,2-bis(aminooxy)ethane,1,3-bis(aminooxy)propane,1,4-bis(aminooxy)butane and three kinds of salicylaldehyde derivatives in anhydrous ethanol solvent.Their complexes were prepared from the salen-type bisoxime derivatives and transition metal salts.The compounds were characterized by elemental analysis,IR,1H NMR and TG-DTA.The results indicated that the novel salen-type bisoxime derivatives were all good tetradentate N2O2-donating ligands and had good capability of coordination with transition metal ions.The reaction conditions were mild and the yield of products was high. |
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| Keywords: | salen-type bisoxime ligand complex synthesis characterization |
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