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低碳铝镇静钢中(CaO)_x(Al_2O_3)_y及CaS的形成与控制
引用本文:王敏,包燕平,刘建华,李太全,吴华杰,崔衡.低碳铝镇静钢中(CaO)_x(Al_2O_3)_y及CaS的形成与控制[J].钢铁,2009,44(12).
作者姓名:王敏  包燕平  刘建华  李太全  吴华杰  崔衡
作者单位:北京科技大学冶金与生态工程学院,北京,100083
摘    要:生产低碳铝镇静钢过程中,为了控制夹杂物形态,一般要对其进行钙处理。如何使钙处理过程中生成液态的钙铝酸盐夹杂是生产控制的难点和重点。通过理论计算得出在一定条件下Ca]-Al]、S]-Al]关系图,以某低碳铝镇静钢为例,当w(Al])为0.03%时,控制w(Ca])为(9~15.8)×10-6,可以生成成分接近(CaO)12(Al2O3)7的液相夹杂。钢中w(S])为30×10-6,w(Al])为0.03%~0.04%,温度降低到1 723 K以下时,在(CaO)12(Al2O3)7上会析出CaS。

关 键 词:铝脱氧钢  钙处理  夹杂物  

Formation and Control of (CaO)_x(Al_2O_3)_y and CaS in Low Carbon Al-Killed Molten Steel
WANG Min,BAO Yan-pin,LIU Jian-hua,LI Tai-quan,WU Hua-jie,CUI Heng.Formation and Control of (CaO)_x(Al_2O_3)_y and CaS in Low Carbon Al-Killed Molten Steel[J].Iron & Steel,2009,44(12).
Authors:WANG Min  BAO Yan-pin  LIU Jian-hua  LI Tai-quan  WU Hua-jie  CUI Heng
Affiliation:WANG Min,BAO Yan-pin,LIU Jian-hua,LI Tai-quan,WU Hua-jie,CUI Heng(Metallurgical and Ecological Engineering School,University of Science and Technology Beijing,Beijing 100083,China)
Abstract:Generally,in order to control the morphologies of inclusions,the low carbon Al-killed steel should be treated with calcium.It's difficult and important to make the inclusions to be liquid(CaO)x(Al2O3)y inclusions though the processing control.Correlation figures between solute calcium and solute aluminum,also between solute sulfur and solute aluminum have been established theoretically.Taking a kind of low carbon Al-killed steel for example,when the solute aluminium is 0.03 percent and the calcium is contro...
Keywords:Al-killed steel  calcium treatment  inclusion  
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