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PE-g-MAH增容改性LDPE/橡实壳纤维复合材料的研究
引用本文:李守海,庄晓伟,王春鹏,储富祥.PE-g-MAH增容改性LDPE/橡实壳纤维复合材料的研究[J].工程塑料应用,2010,38(11).
作者姓名:李守海  庄晓伟  王春鹏  储富祥
作者单位:中国林业科学研究院林产化学工业研究所;浙江森林资源生物与化学利用重点实验室;
基金项目:国家863计划资助项目,浙江省森林资源生物与化学利用重点实验室开放课题
摘    要:采用熔融挤出法制备了低密度聚乙烯(LDPE)/橡实壳纤维(AS)木塑复合材料.研究了增容剂聚乙烯接枝马来酸酐(PE-g-MAH)对LDPE/AS木塑复合材料的影响.结果表明,PE-g-MAH是一种优良的增容剂,当其质量分数为5%时,LDPE/AS复合材料的拉伸强度比未添加时提高77.6%,弯曲强度提高83.8%,缺口冲击强度基本保持在5.0 kJ/m2.SEM分析表明,PE-g-MAH改善了AS与LDPE基体材料的相容性.DMA和DSC测试表明,PE-g-MAH能有效改善两相之间的界面相容性,并从根本上改善LDPE基体材料的性能.

关 键 词:橡实壳纤维  低密度聚乙烯  木塑复合材料  增容剂

STUDY OF COMPATIBILIZATION AND MODIFICATION BEHAVIOR OF PE-g-MAH ON LOW DENSITY POLYETHYLENE/ACORN SHELL FIBRE COMPOSITES
Li Shouhai,Zhuang Xiaowei,Wang Chunpeng,Chu Fuxiang.STUDY OF COMPATIBILIZATION AND MODIFICATION BEHAVIOR OF PE-g-MAH ON LOW DENSITY POLYETHYLENE/ACORN SHELL FIBRE COMPOSITES[J].Engineering Plastics Application,2010,38(11).
Authors:Li Shouhai  Zhuang Xiaowei  Wang Chunpeng  Chu Fuxiang
Affiliation:Li Shouhai1,Zhuang Xiaowei1,2,Wang Chunpeng1,Chu Fuxiang1(1.Institute of Chemical Industry of Forest Products,CAF,Nanjing 210042,China,2.Key Laboratory for Biological and Chemical Utilizing of Forest Resources of Zhejiang,Hangzhou 310023,China)
Abstract:The bio-composites of low density polyethylene(LDPE)/acorn shell(AS) fibre were produced by hot-melt extrusion method.The effects of PE-g-MAH on composites were studied.The results suggested that PE-g-MAH was an excellent compatibilizer for LDPE/AS composite.When the content of PE-g-MAH was 5% under the condition of 50% AS content,compared the mechanical properties of modifying composite with those of composite without compatibilizer,the tensile strength increased by 77.6%,flexural strength increased by 83....
Keywords:acorn shell fibre  low density polyethylene  wood-palstic composites  compatibilizer  
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