Enhanced energy storage properties of BaO-K2O-Nb2O5-SiO2 glass ceramics obtained through microwave crystallization |
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| Authors: | Jia Tian Shujian Wang Ke Yang Jingran Liu Jiwei Zhai Bo Shen |
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| Affiliation: | Key Laboratory of Advanced Civil Engineering Materials of Ministry of Education, Functional Materials Research Laboratory, School of Materials Science & Engineering, Tongji University, 4800 Caoan Road, Shanghai 201804, China |
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| Abstract: | BaO-K2O-Nb2O5-SiO2 (BKNS) glass ceramics were prepared by microwave crystallization of transparent glass matrices and the effects of microwave treatment temperature on their dielectric performances, phase structure, microstructure and breakdown strength (BDS) were investigated systematically. X-ray diffraction results suggested that microwave treatment had no significant influence on the type of precipitated phases. The microstructure of the glass ceramics was remarkably optimized via microwave treatment. The dielectric constant and breakdown strength of microwave-treated samples were significantly improved as compared with conventional-heated samples at the same temperature. The maximum theoretical energy storage density of microwave-treatment samples at 750?°C reached 12.7?J/cm3, which was larger than that of the conventional-heated samples (8.6?J/cm3). |
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| Keywords: | Glass ceramics Microwave treatment Dielectric properties Breakdown strength Energy storage density |
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