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Synthesis and optical properties of ZnS hollow spheres from single source precursor
Authors:Caixia Song  Debao Wang
Affiliation:a College of Materials Science and Engineering, Qingdao University of Science & Technology, Qingdao 266042, PR China
b College of Chemistry and Molecular Engineering, Qingdao University of Science & Technology, Qingdao 266042, PR China
Abstract:
A facile one-pot synthesis of ZnS hollow spheres has been carried out via a chemical transformation induced inside-out Ostwald ripening process from a single source precursor. The size and shell thickness of the ZnS hollow spheres can be controlled by adjusting the reaction temperature and reaction time, respectively. Photoluminescence spectra show a dominant emission peak at 470 nm accompanied by several weaker peaks. UV-vis measurement reveals that the obtained ZnS hollow spheres exhibit “hollow effect”. The formation process of ZnS hollow spheres has been discussed.
Keywords:A. Nanostructures   B. Chemical synthesis   C. Electron microscopy   D. Luminescence
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