| 乙烯齐聚合成α-烯烃用催化剂研究进展 |
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| 引用本文： | 于部伟,张宝军,陈胜利,李建忠,王斯晗,曲家波.乙烯齐聚合成α-烯烃用催化剂研究进展[J].精细石油化工进展,2007,8(6):51-58. |
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| 作者姓名： | 于部伟 张宝军 陈胜利 李建忠 王斯晗 曲家波 |
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| 作者单位： | 1. 中国石油大学重质油国家重点实验室,北京,102249
2. 中国石油天然气股份有限公司大庆化工研究中心,大庆,163714 |
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| 基金项目： | 中国石油重点科技攻关项目 |
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| 摘 要： | 综述了近年来国内外乙烯齐聚用催化剂研究进展.催化剂主要有烷基铝系、钛系、镍系、铁系、铬系、锆系等.其中镍系催化剂具有活性高、选择性好、产品分布可调、反应条件温和等优良性能.铬系催化剂则可以高选择性的合成1-已烯和1-辛烯.
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| 关 键 词： | 催化剂 乙烯 齐聚 α-烯烃 已烯 辛烯 乙烯齐聚 齐聚合成 烯烃 铬系催化剂 研究进展 Ethylene Catalysts Research Progress 辛烯 已烯 高选择性 优良性能 反应条件 产品分布 活性 镍系催化剂 锆系 铁系 铝系 |
| 修稿时间： | 2007-03-14 |
Progress on Research of Catalysts for Ethylene Oligomerizafion to α-Olefins |
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| Yu Buwei,Zhang Baojun,Chen Shengli,Li Jianzhong,Wang Sihan,Qu Jiabo.Progress on Research of Catalysts for Ethylene Oligomerizafion to α-Olefins[J].Advances in Fine Petrochemicals,2007,8(6):51-58. |
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| Authors: | Yu Buwei Zhang Baojun Chen Shengli Li Jianzhong Wang Sihan Qu Jiabo |
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| Affiliation: | 1. State Key Lab of Heavy Oil Processing, China University of Petroleum, Beijing 102249; 2. Daqing Petrochemical Research Centre, PetroChina Company Limited, Daqing 163714 |
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| Abstract: | Progress on developing aluminum-,titanium-,nickel-,iron-,chromium-,and zirconium-based catalysts for ethylene oligomerization was reviewed. Nickel-based catalysts had excellent performances such as high catalytic activity,high selectivity,easily-controlled oligomers distribution and moderate reaction conditions. Chromium-based catalysts were used to produce 1-hexene and 1-octene with high selectivities. |
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