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Spectral Properties and Upconversion Luminescence of Er^3+, yb^3+: BaWO4 Crystal
引用本文:Lü Chao. Spectral Properties and Upconversion Luminescence of Er^3+, yb^3+: BaWO4 Crystal[J]. 中国稀土学报(英文版), 2007, 25(5): 578-584. DOI: 10.1016/S1002-0721(07)60566-3
作者姓名:Lü Chao
作者单位:[1]College of Mcferials Science and Engineering University of Technology Beijing Beijing 100022, China [2]College of Applied Science, University of Technology Beijing Beijing 100022, China [3]Key Laborctory of Optical Physics, Institute of Physics, Chinese Academy of Sciences, Beij'ing 100080, China
基金项目:Project supported by the Key Laboratory of 0ptical Physics, Institute of Physics, Chinese Academy of Sciences
摘    要:
The optical quality of Er^3+, yb^3+: BaWO4 crystal was gown by Czochralski method. Absorption spectra were measured and energy levels were assigned. According to Judd-Ofelt theory, the spectral strength parameters of Er^3+ ion were fitted to beΩ2 =0.3926 x 10^-20 cm^2, Ω4 =0.0721×10^-20 cm^2, Ω6 =0.0028 ×10.20 cm^2. Emission peaks centered at around 523,544 and 670 nm were observed under 334 nm He-Cd laser excitation and emission peaks centered at 1001 and 1534 nm were detected under 976 nm laser excitation. Strong green emission was also observed when the crystal was pumped with 808 nm and 976 nm laser. The mechanisms of frequency upconversion and sensitization were analyzed.

关 键 词:激光晶体      稀土元素  化学结构
文章编号:1002-0721(2007)05-0578-07
收稿时间:2006-11-05
修稿时间:2006-11-05

Spectral Properties and Upconversion Luminescence of Er, Yb: BaWO4 Crystal
Zang , Xie Liyan, Li Xiao, Guo Kai, Liu Guoqing, Zou Yulin, L,#xfc; Chao,Feng Baohua. Spectral Properties and Upconversion Luminescence of Er, Yb: BaWO4 Crystal[J]. Journal of Rare Earths, 2007, 25(5): 578-584. DOI: 10.1016/S1002-0721(07)60566-3
Authors:Zang , Xie Liyan, Li Xiao, Guo Kai, Liu Guoqing, Zou Yulin, Lü   Chao,Feng Baohua
Affiliation:aCollege of Materials Science and Engineering, University of Technology Beijing, Beijing 100022, China;bCollege of Applied Science, University of Technology Beijing, Beijing 100022, China;cKey Laboratory of Optical Physics, Institute of Physics, Chinese A cademy of Sciences, Beijing 100080, China
Abstract:
The optical quality of Er3+, Yb3+: BaWO4 crystal was grown by Czochralski method. Absorption spectra were measured and energy levels were assigned. According to Judd-Ofelt theory, the spectral strength parameters of Er3+ ion were fitted to be ω2 =0.3926 x 10−20 cm2, ω4 =0.0721 x 10−20 cm2, ω6 =0.0028 x 10−20 cm2. Emission peaks centered at around 523, 544 and 670 nm were observed under 334 nm He-Cd laser excitation and emission peaks centered at 1001 and 1534 nm were detected under 976 nm laser excitation. Strong green emission was also observed when the crystal was pumped with 808 nm and 976 nm laser. The mechanisms of frequency upconversion and sensitization were analyzed.
Keywords:laser crystal  upconversion  Er3 ,Yb3 : BaWO4 crystal  rare earths
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