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石墨/LiFePO4电池循环过程的研究
引用本文:张建,杨传铮,娄豫皖,夏保佳. 石墨/LiFePO4电池循环过程的研究[J]. 电源技术, 2012, 36(2): 165-168
作者姓名:张建  杨传铮  娄豫皖  夏保佳
作者单位:中国科学院上海微系统与信息技术研究所,上海,200050
基金项目:上海市科委纳米技术专项,中国科学院院地合作项目,上海市自然科学基金
摘    要:利用X射线衍射分析对石墨/LiFePO4电池循环过程中正、负极活性材料和隔膜的晶体结构及精细结构的变化进行了研究。结果发现,电池的充放电容量随循环的进行先增加而后逐渐降低的现象与正极活性材料及隔膜的精细结构在循环过程中变化的共同作用有关,而与负极活性材料的关系不大。

关 键 词:石墨/LiFePO4电池  循环性能  精细结构  X射线衍射

Research of cycle process of graphite/LiFePO4 battery
ZHANG Jian , YANG Chuan-zheng , LOU Yu-wan , XIA Bao-jia. Research of cycle process of graphite/LiFePO4 battery[J]. Chinese Journal of Power Sources, 2012, 36(2): 165-168
Authors:ZHANG Jian    YANG Chuan-zheng    LOU Yu-wan    XIA Bao-jia
Affiliation:(Shanghai Institute of Micro-system and Information Technology,Academic Science of China,Shanghai 200050,China)
Abstract:The variations of structure and fine structure of electrode materials and separator in a graphite/LiFePO4 battery during cycle process were studied by X-ray diffraction.It is revealed that,the capacity of the battery firstly increase and then degrease with the increase of cycles.The reason is related with the changes of fine structure of the positive active material and separator during cycle process.
Keywords:graphite/LiFePO4 battery  cycle performance  fine structure  X-ray diffraction
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