| 酞菁钴/MCM-41的合成、表征及催化性质 |
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| 引用本文： | 朱淑英,魏征,尹丽娜,董勤,郭卓.酞菁钴/MCM-41的合成、表征及催化性质[J].沈阳化工学院学报,2007,21(2):109-112. |
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| 作者姓名： | 朱淑英 魏征 尹丽娜 董勤 郭卓 |
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| 作者单位： | 沈阳化工学院,材料科学与工程学院,辽宁,沈阳,110142 |
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| 基金项目： | 辽宁省教育厅高等学校科学研究项目计划(A)类 |
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| 摘 要： | 采用共混(one-pot)方法,将有机功能材料酞菁钴(CoPc)组装进介孔分子筛MCM-41孔道中,合成纳米复合材料CoPc/MCM-41,并利用X-射线粉末衍射,Uv-vis,N2吸附,TEM等方法对其进行表征.研究结果表明:CoPc成功地组装进介孔分子筛MCM-41的孔道中,并以单体的形式存在;同时对其催化性质进行了研究,因为CoPc在MCM-41中以单体的形式存在,因此组装体显示出比体相CoPc更加优异的催化性能,为新型催化剂的研究与开发提供了借鉴与经验.
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| 关 键 词： | 共混 催化性质 |
| 文章编号： | 1004-4639（2007）02-0109-04 |
| 修稿时间： | 2006-04-10 |
Synthesis, Characterization and Catalytic Performance of CoPc/MCM-41 |
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| ZHU Shu-ying,WEI Zheng,YIN Li-na,DONG Qin,GUO Zhuo.Synthesis, Characterization and Catalytic Performance of CoPc/MCM-41[J].Journal of Shenyang Institute of Chemical Technolgy,2007,21(2):109-112. |
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| Authors: | ZHU Shu-ying WEI Zheng YIN Li-na DONG Qin GUO Zhuo |
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| Affiliation: | Shenyang Institute of Chemical Technology, Shenyang 110142, China |
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| Abstract: | Functional materials CoPc had been successfully incorporated into mesoporous sieve MCM-41 by one-pot methods.The assembly materials were characterized by XRD,UV-Vis,N2 adsorption-desorption and TEM.At the same time,the catalytic behavior of these assembly materials was studied.The assembly materials exhibited better catalytic properties compared to the bulk CoPc because of existence of the monomer of CoPc.The catalytic behavior of CoPc/MCM41 was higher than that of CoPc. |
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| Keywords: | CoPc MCM-41 |
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