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Rheological,thermal and morphological properties of polyethylene terephthalate/polyamide 6/rice husk ash composites
Authors:Anna Raffaela de Matos Costa  Juliana Cysneiros Lima  Raquel dos Santos  Lhaira Souza Barreto  Mariana Alves Henrique  Laura Hecker de Carvalho  Yêda Medeiros Bastos de Almeida
Affiliation:1. Department of Chemical Engineering, Federal University of Pernambuco, Recife, Brazil;2. Department of Materials Engineering, Federal University of Campina Grande, Campina Grande, Brazil;3. Postgraduate in Materials Science, Federal University of Pernambuco, Recife, Brazil
Abstract:This work deals with the rheological, morphological, and thermal properties of composites having poly(ethylene terephthalate) (PET), polyamide-6 (PA6), and their blends as matrices, and rice husk ash (RHA) as a filler. The study determines the effect of composition on the change in viscosity and rate of degradation during processing in a torque rheometer. Our data indicates that thermal stability and degradation during processing depend on matrix composition and filler concentration. SEM micrographs show both partial adhesion of the filler to the matrices and filler pullout. Optical microscopy shows particle agglomeration and that agglomerate size increased with filler content. FTIR investigates the shifting of absorption bands of PET/PA6 composite after the addition of RHA and attributes the selective dispersion of RHA to the formation of hydrogen bonds. Our data supports the idea that filler employed here is an option to develop polymer composites with improved properties.
Keywords:blends  degradation  polyamides  polyesters  rheology
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