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Feasibility of using polycarbonate as a substrate of thin film composite membrane in forward osmosis
Authors:Z Alihemati  S A Hashemifard  T Matsuura  A F Ismail
Affiliation:1. Sustainable Membrane Technology Research Group (SMTRG), Faculty of Petroleum, Gas and Petrochemical Engineering (FPGPE), Persian Gulf University (PGU), Bushehr, Iran;2. Advanced Membrane Technology Research Centre (AMTEC), Universiti Teknologi Malaysia, Skudai, Malaysia

Department of Chemical and Biological Engineering, University of Ottawa, Ottawa, Canada;3. Advanced Membrane Technology Research Centre (AMTEC), Universiti Teknologi Malaysia, Skudai, Malaysia

Abstract:In the present study, thin film composite (TFC) forward osmosis (FO) membranes with polycarbonate (PC (and polyether sulfone (PES) as substrates were fabricated to investigate the impact of the structural parameters of substrate on the performance of the membranes. Firstly, the substrates were prepared by Loeb-Sourirajan method. Characterization techniques including FESEM, contact angle measurement, pure water flux, gas permeability test, and tensile test were applied to investigate the properties of the substrates. After preparing suitable substrates, active layers were fabricated via interfacial polymerization (IP) technique. The performance and characterization test showed that PC is a relatively hydrophilic polymer with a good property for using as a substrate of FO TFC membrane but as the result of gas permeability test show, this membrane has large surface pore size in comparison with PES membrane. Mean pore size of PC and PES membrane is 378 and 139 nm, respectively. Also, the results show that the effective surface porosity of PC (285, 1/m) is more than PES (213, 1/m) substrate.
Keywords:desalination  forward osmosis  polycarbonate  thin film composite membrane
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